Germanium sulfide (GeS2) is a white powder with an orthorhombic crystal structure, known for its role as a minor metal sulfide. While it offers unique properties, GeS2 is relatively unstable, particularly at high temperatures, where it tends to sublimate and oxidize. In the presence of moisture or an inert atmosphere, germanium disulfide dissociates, when heated its molten state turns into a bright brown, transparent body, showcasing its complex thermodynamic behavior.
Germanium Sulfide
CAS No.:12025-34-2 | EINECS No.:234-705-1 | Molecular Formula:GeS2 | Molecular Weight:136.71 |
Density:2.19 | Melting Point:800℃ |
Chemical Properties:
- Solubility:Germanium disulfide is insoluble in water and inorganic acids, including even strong acids.However,it can dissolve in thermokalite,undergoing transformation into germanium amide.
- Oxidation:GeS2 begins to oxidize at temperatures between 260-280℃ in the presence of air.When oxidized by hydrogen peroxide, it forms germanium dioxide(GeO2).
- Volatility:Germanium disulfide is prone to sublimation and oxidation at elevated temperatures,making handling and storage conditions critical to maintaining stability.
Applications
1.Semiconductor Material:GeS2 plays a crucial role in semiconductor technology due to its unique electrical properties.It is used in the fabrication of various semiconductor devices that require stable and efficient performance under high-temperature conditions.
2.Energy Storage:GeS2 is also being explored as an energy storage material,leveraging its high stability and potential for use in energy conversion and storage applications.
3.Catalyst and Chemical Synthesis:GeS2 serves as a precursor for other germanium-based compounds and finds applications in the preparation of germanium dioxide and other related materials in chemical synthesis.
4.Optoelectronic Devices:Due to its semiconducting properties, germanium disulfide is being researched for potential use in optoelectronic devices such as light sensors and infrared detectors.
5.Other Advanced Material Applications:Germanium sulfide’s properties make it suitable for high-performance applications in electronics, optoelectronics, and materials science.