Indium fluoride (InF3) is a white powder that belongs to the category of minor metal fluorides.It has important applications in various industries,particularly in the production of non-oxide glasses and as a catalyst in organic synthesis.With the molecular formula of InF3 and a molecular weight of 171.82g/mol,indium fluoride has excellent chemical properties,including high thermal stability and resistance to oxidation.It is sparingly soluble in water,dissolving only slightly at a concentration of 0.04g per 100g of water,but is highly reactive in other chemical environments.Indium fluoride is typically produced from indium metal,which is used as the primary raw material.
Indium fluoride plays an important role in many industrial processes,especially in applications requiring specialized materials such as non-oxide glasses,catalysis,and semiconductors.It is often handled in its anhydrous form,though it can also exist as a trihydrate,indium(III) fluoride trihydrate(InF3.3H2O),under certain conditions.
Indium Fluoride
CAS No.:7783-52-0 | EC No.:232-005-0 | Molecular Formula: InF3 | Molecualr Weight:171.82 |
Density:4.39 | Melting Point:1170℃ | Boiling Point:>1200℃ |
Indium fluoride exhibits a number of characteristics that make it valuable in various applications.Its high melting point(1170℃)and boiling point(>1200℃)make it suitable for high-temperature processes,such as in the production of glasses and ceramics.As a fluoride compound,it is relatively stable in high-temperature environments,which is a key factor in its use as a catalyst in certain chemical reactions.The compound’s relatively low solubility in water(0.04g per 100g of water) and its tendency to hydrolyze when reduced make it a specialized material,requiring controlled environments during handling and applications.
Synthesis and Formation:Indium fluoride is synthesized from indium metal(In) through a fluorination process,where it reacts with fluorine or hydrofluoric acid(HF) to form the fluoride compound.When reduced,indium trifluoride(InF3) can be converted to indium(II) fluoride(InF2),but this compound is prone to hydrolysis and requires specific conditions to maintain its stability.
Additionally,indium fluoride can exist as trihydrate(InF3.3H2O) when exposed to moisture,which alters its physical properties.The presence of water in the crystalline structure of the trihydrate form affects its solubility and reactivity,so handling the anhydrous form is often preferred in most industrial processes.
Applications
1.Non-Oxide Glass Manufacturing:One of the primary applications of indium fluoride is in the production of non-oxide glasses,which are used in a variety of optical and electronic devices.Non-oxide glasses are important in applications where traditional oxide glasses do not perform well,such as in fiber optics and infrared optics.The fluoride component in indium fluoride imparts desirable optical properties,such as high transparency and low refractive index,which are essential for the production of high-quality glass for optical fibers and lenses used in telecommunications,medical imaging,and other advanced technologies.
2.Catalysis in Organic Synthesis:Indium trifluoride is a well-regarded catalyst in organic chemistry,particularly for the addition of trimethylsilyl cyanide(TMSCN) to aldehydes.This reaction leads to the formation of cyanohydrins,which are valuable intermediates in the production of pharmaceuticals,agrochemicals,and fine chemicals.The unique catalytic properties of InF3 allow it to facilitate this transformation under mild conditions,making it a desirable choice for synthetic chemists seeking efficiency and selectivity in their reactions.
3.Semiconductor Industry:As a fluoride compound,indium fluoride has potential applications in the semiconductor industry.Indium-based compounds are already widely used in semiconductors due to indium’s ability to form conductive alloys with other metals, such as tin and gallium.Indium fluoride,with its unique properties,can be utilized in various semiconductor fabrication processes,particuarly in the creation of specialized coatings and thin films that require precise control of optical and electrical properties.It can also be used as a dopant or material in the production of semiconductor devices,including LEDs and photovoltaic cells.
4.Fluoride Coatings and Surface Treatment:Indium trifluoride is sometimes employed in the development of specialized coatings for metal surfaces,particularly those used in the aerospace and electronics industries.These coatings are designed to improve corrosion resistance and enhance the performance of materials exposed to extreme conditions.Indium fluoride-based coatings can be used to create hydrophobic surfaces or to prevent oxidation in metals,increasing their longevity and efficiency in industrial applications.
5.Fluorine-Containing Compounds:Indium trifluoride is also utilized in the synthesis of other fluorine-containing compounds.It is a precursor for the production of indium-based salts,such as indium hexafluoride(InF6),and may be used in the production of specialty fluoropolymers and other fluorine-rich chemicals.These fluorinated compounds are often used in advanced materials that require high thermal stability and chemical resistance.
6.Photovoltaic and Display Technologies:In the field of photovoltaic technologies,indium fluoride may play a role in the development of thin-film solar cells.The optical properties of indium fluoride make it a potential candidate for coatings and materials that help to enhance the efficiency of light absorption and conversion in solar cells.Additionally,its role in transparent conductive coatings may also extend to dispaly technologies,where it could contribute to the development of more efficient and durable screens for electronics.
6.Research and Development:Indium(III) fluoride is commonly used in research and development settings,particularly in laboratories focused on material science and inorganic chemicstry.Researchers utilize indium fluoride in the synthesis of other compounds,as a catalyst in sythetic chemistry,and in the creation of novel materials with specialized properties for applications in optics, electronics and energy storage.
Challenges and Handling:Due to its tendency to hydrolyze and form various hydrated forms,handling indium fluoride requires special care to maintain its anhydrous state.In industrial applications,it is typically stored in sealed containers to protect it from moisture in the air.Additionally,when reduced, indium fluoride can form InF2, which is more prone to oxidation and requires controlled conditions for storage and use.
Indium(III) fluoride is a versatile and important material with a range of applications in industries such as optics,organic synthesis,semiconductors,and advanced materials.Its role in the production of non-oxide glasses,catalysis,and other chemical processes makes it an indispensable compound in many high-tech fields.As research in materials science and chemistry continues to advance,the demand for high-purity indium fluoride and its derivates is expected to grow,expanding its use in innovative applications across multiple sectors.
At Zegen Advanced Materials,we are committed to providing high-quality indium(III) fluoride and other specialized compounds,ensuring that our clients have access to the materials they need for cutting-edge research and industrial applications.